Journal of Crystal Growth, Vol.253, No.1-4, 183-189, 2003
Crystallographic control in thin-layer silicon depositions by atmospheric-pressure iodine vapor transport
Silicon thin layers that are either highly textured polycrystalline, randomly oriented polycrystalline, or epitaxial have been deposited by the technique of atmospheric-pressure iodine vapor transport on silicon or non-silicon substrates. Strongly [1 1 0]-textured polycrystalline silicon films are obtained by starting with a relatively low starting substrate temperature of 700degreesC, to increase nucleation density, then ramping up to 900degreesC at the end to increase growth rate. Alternatively, if a higher constant temperature of 900degreesC is used, we obtain polycrystalline silicon layers with randomly oriented large grains of similar to 20 mum in average size. When a still higher initial substrate temperature of 1000degreesC is used to eliminate condensation of silicon iodides at the interface, high-quality epitaxial silicon layers are grown on silicon substrates. (C) 2003 Elsevier Science B.V. All rights reserved.
Keywords:interfaces;polycrystalline deposition;atmospheric-pressure iodine vapor transport;semiconducting silicon