Journal of Crystal Growth, Vol.272, No.1-4, 506-514, 2004
Growth of AlxGa1-xN-layers on planar and patterned substrates
AlxGal-xN-layers are applied in various devices based on group-III-nitride semiconductors. Crystalline quality, composition and morphology need to be controlled by properly adjusting growth processes. Here, we report on AlGaN growth by low-pressure MOVPE on planar and patterened surfaces of sapphire and 6H-SiC(0001) with focus on Al-incorporation and lateral growth. All layers show good surface morphology, near bandedge luminescence and no sign of phase separation (Al-concentration < 50%). The Al-incorporation depends critically on growth parameters. For high pressures of 200 mbar Al is hardly incorporated which can be understood as a result of prereactions involving TMAl and NH3. For patterened substrates PL indicates lateral variation in Al composition as a consequence of mass transport and a reduced lateral growth rate. (C) 2004 Elsevier BN. All rights reserved.
Keywords:atomic force microscopy;high resolution X-ray diffraction;surfaces;metalorganic vapor phase epitaxy;nitrides;semiconducting III-V materials;semiconducting ternary compounds