Journal of Crystal Growth, Vol.281, No.1, 17-31, 2005
Growth of thick GaN layers with hydride vapour phase epitaxy
In this paper we describe recent experimental efforts to produce high quality thick (>= 300 mu m) GaN layers on sapphire, the removal of such a layer from the sapphire substrate, and the properties of the so obtained free-standing GaN material. The growth process is described in some detail in the vertical reactor geometry used in this work. Defects like dislocations, micro-cracks and pits produced during growth are discussed, along with procedures to minimize their concentration on the growing surface. The laser lift-off technique is shown to be a feasible technology, in particular if a powerful laser with a large spot size can be used. A major problem with the free-standing material is the typically large bowing of such a wafer, due to the built in defect concentrations near the former GaN-sapphire interface. This bowing typically causes a rather large width of the XRD rocking curve of the free-standing material, while optical data confirm virtually strain free material of excellent quality at the top surface. (c) 2005 Elsevier B.V. All rights reserved.
Keywords:characterization;computer simulation;defects;chloride vapour phase deposition;gallium nitride