Journal of Crystal Growth, Vol.298, 268-271, 2007
Growth of low dislocation density GaN using transition metal nitride masking layers
Films of Sc and Ti (5 and 20nm thick) were deposited on 500 nm GaN/Al2O3 templates, then annealed in mixed NH3 and H-2 at 1070 degrees C in an MOCVD reactor to produce ScN and TiN films. This resulted in a dense array of holes in the TiN layers, but had little effect on ScN layers. The dislocation densities in GaN grown on the masked templates were reduced significantly from 5.0 +/- 0.5 x 10(9) cm(-2) on the templates to 1.5 +/- 0.2x 10(8) cm(-2) on the thin TiN layers and were reduced almost a 100-fold to 6.4 +/- 0.7 x 10(7) cm(-2) on the thin ScN layers, despite the absence of holes in the latter. TiN layers produced GaN films under compressive residual stress and ScN layers gave GaN films under tensile residual stress; the levels of stress varied with mask thickness. The masking layers therefore provide a convenient method to control both dislocation densities and wafer curvature, both of which are necessary for successful device fabrication. (c) 2006 Published by Elsevier B.V.