Journal of Crystal Growth, Vol.303, No.2, 629-631, 2007
Growth by the heat exchanger method of NaBiW2O8 and Na5B2P3O13 crystals
In this paper, we present the results of our attempt to grow NaBiW2O8 (NBW) and Na5B2P3O13 (NBP) crystals by the heat exchanger method (HEM). This method is slightly different from the Bridgman technique: the crucible is kept fixed in the setup and the center of the crucible bottom is cooled by a variable helium gas flow. It allows very good control of the growth rate and minimizes parasitic crystallization at the crucible walls. First experiments for growing these two materials by the HEM technique have shown very promising results with single-crystal sizes of few cubic centimetres. (C) 2007 Elsevier B.V. All rights reserved.
Keywords:growth from melt;HEM;phosphates;tungstates;non-linear optics materials;scintillator materials