화학공학소재연구정보센터
Applied Surface Science, Vol.212, 679-683, 2003
Contact resistivity between tungsten and impurity (P and B)-doped Si1-x-yGexCy epitaxial layer
Contact resistivity between tungsten and in situ impurity (P and B)-doped Si1-x-yGexCy films with 0 less than or equal to x less than or equal to 0.7, 0 less than or equal to00 y less than or equal to 0.02 has been investigated. In the case of the P-doped Si1-x-yGexCy films, the contact resistivity decreases with increasing the carrier concentration, independently of the Ge and C fraction. Because P atoms become electrically inactive with increasing the Ge and C fractions, lower Ge and C fractions are necessary to reduce the contact resistivity. By growing the multi-layer P-doped epitaxial Si with a high carrier concentration of 4 x 10(20) cm(-3) at a very low temperature of 450 degreesC on the P-doped Si1-x-yGexCy film, very low contact resistivity of 6.5 x 10(-8) Omega cm(2) is achieved. On the other hand, in the case of the B-doped Si1-x-yGexCy films, the contact resistivity decreases with increasing the Ge fraction and scarcely depends on C fraction at a specified carrier concentration, and is typically 25 and 57% lower for x = 0.44 and 0.7 than that for Si, respectively. For the B-doped Si0.56Ge0.44 films with a high carrier concentration of 6 x 10(20) cm(-3), very low contact resistivity is obtained to be 3.8 x 10(-8) Omega cm(2). These results demonstrate that low contact resistivity is caused by the lowering of schottky barrier height between metal and the B-doped film, due to the valence band shift. (C) 2003 Elsevier Science B.V. All rights reserved.