Applied Surface Science, Vol.253, No.5, 2752-2757, 2006
High-density plasma etching of indium-zinc oxide films in Ar/Cl-2 and Ar/CH4/H-2 chemistries
The dry etching characteristics of transparent and conductive indium-zinc oxide (IZO) films have been investigated using an inductively coupled high-density plasma. While the CI2-based plasma mixture showed little enhancement over physical sputtering in a pure argon atmosphere, the CH4/H-2/Ar chemistry produced an increase of the IZO etch rate. On the other hand, the surface morphology of IZO films after etching in At and Ar/Cl-2 discharges is smooth, whereas that after etching in CH4/H-2/Ar presents particle-like features resulting from the preferential desorption of In and O-containing products. Etching in CH4/H-2/Ar also produces formation of a Zn-rich surface layer, whose thickness (similar to 40 nm) is well-above the expected range of incident ions in the material (similar to 1 nm). Such alteration of the IZO layer after etching in CH4/H-2/Ar plasmas is expected to have a significant impact on the transparent electrode properties in optoelectronic device fabrication. (c) 2006 Elsevier B.V. All rights reserved.
Keywords:indium-zinc oxide;dry etching