Communication: A four-coordinate azaporphyrin, FeOETAP (see Figure), is reported that has temperature- and field-dependent properties different from those of other four-coordinate iron(II) porphyrins and related macrocycles, displaying an apparent canted ferromagnetic state. This behavior is compared to that of M2+ (OETAP), where M = Mn, Co, Ni, Cu, and Zn.