Advanced Materials, Vol.15, No.24, 2101-2101, 2003
Molecular-scale interface engineering of TiO2 nanocrystals: Improving the efficiency and stability of dye-sensitized solar cells
Co-grafting an amphiphilic polypyridyl ruthenium sensitizer and 1-decylphosphonic acid on TiO2 semiconductor nanocrystals has resulted in a long-term thermally stable dye-sensitized solar cell (see Figure) with higher than 7 % power conversion efficiency. The extraordinary stability of this high-efficiency device under both thermal stress and light soaking matches the durability criteria for outdoor applications of solar cells.