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Macromolecular Rapid Communications, Vol.16, No.4, 231-237, 1995
LIQUID-CRYSTALLINE POLYIMIDES .16. CHIRAL THERMOTROPIC COPOLY(ESTER-IMIDE)S BASED ON ISOSORBIDE AND N-(4-CARBOXYPHENYL)TRIMELLITIMIDE
A series of chiral copoly(ester-imide)s was prepared by polycondensation of N-(4-carboxy-phenyl)trimellitimide with mixtures of isosorbide and phenylhydroquinone. All copolyesters are non-crystalline. They form a cholesteric melt, when containing more than 50 mol-% of phenylhydroquinone. Containing 5 or 10 mol-% of isosorbide a ''Grand-Jean'' texture is detected above 300 degrees C and 350 degrees C, respectively.