Macromolecular Rapid Communications, Vol.18, No.4, 319-324, 1997
Gas phase polymerization of ethylene with a silica-supported metallocene catalyst: Influence of temperature on deactivation
Ethylene was polymerized at 5 bar in a stirred powder bed reactor with silica supported rac-Me2Si[Ind](2)ZrCl2/methylaluminoxane (MAO) at temperatures between 40 degrees C and 80 degrees C using NaCl as support bed and triethylaluminium (TEA) as a scavenger for impurities. For this fixed recipe and a given charge of catalyst, the average catalyst activity is reproducible within 10% for low temperatures. The polymerization rate and the rate of deactivation increase with increasing temperature. The deactivation could be modeled using a first order dependence with respect to the polymerization rate.