화학공학소재연구정보센터
Macromolecular Rapid Communications, Vol.22, No.6, 451-455, 2001
An analysis of the solvent effects on the monomer reactivity ratios using the copolymer glass transition temperatures
The glass transition temperatures (T-g) of styrene-butyl acrylate copolymers obtained by free radical polymerization in bulk,and in 3 mol . L-1 benzene and benzonitrile solutions, have been measured using differential scanning calorimetry (DSC) to verity the bootstrap effect previously reported for this system. The corresponding values have been correlated with copolymer composition and microstructure using the Johnston equation.