Reaction Kinetics and Catalysis Letters, Vol.70, No.2, 219-226, 2000
Catalysis involving multicentered species on nonuniform surfaces, 1. Adsorption
The multi-centered nature of adsorption as well as adsorbate-adsorbate interactions is discussed. The Bragg-Williams approximation of the lattice gas model was chosen for the description of these interactions. A derivation of adsorption isotherm based on statistical mechanics is presented.