Reaction Kinetics and Catalysis Letters, Vol.79, No.2, 263-269, 2003
Limiting high pressure rate coefficients for the Ho+No2 -> HONO2 reaction on ab initio potential energy surfaces
Phase space limiting high pressure rate coefficients for the title reaction on ab initio potential energy surfaces have been calculated at 50-600 K. Calculated rigidity factors at different levels of theory are presented. The best limiting high pressure rate coefficient obtained at 300 K, 4.0 x 10(-11) cm(3) molecule(-1) s(-1), cornpares very well with the latest IUPAC recommended value.