Reaction Kinetics and Catalysis Letters, Vol.88, No.2, 225-232, 2006
Effects of ceria addition and pre-calcination temperature on performance of cobalt catalysts for Fischer-Tropsch synthesis
The effect of ceria addition on the performance of 10 wt.% Co catalysts supported on SiO2 and Al2O3 for Fischer-Tropsch synthesis has been investigated. The catalysts were prepared by impregnation method and characterized by X-ray diffraction technique. The catalytic tests (P = 1 atm, T = 488 K, H-2/CO = 2, GHSV = 1800 h(-1)) indicate that with addition of ceria, significant changes in CO conversion and hydrocarbon selectivities are observed. Also, the experiments show that the performance of 10 wt.% Co-CeO2/Al2O3 depends on the ceria concentration as well as on the pre-calcination temperature.