기상 중합법에 의한 Nylon 6-Polypyrrole Conductive Composite Film의 제조와 성질

임승순; 강은영; 변성원

Polymer(Korea), Vol.14, No.1, 62-69, February, 1990

Export Citation

기상 중합법에 의한 Nylon 6-Polypyrrole Conductive Composite Film의 제조와 성질

Preparation and Properties of Nylin-Polypyrrole Conductive Composite Films Prepared by Gas State Polymerization

임승순, 강은영, 변성원

초록

FeCl₃를 함유하는 Nylon 6 film을 pyrrole monomer의 증기에 노출시켜 높은 전기전도성을 갖는 Nylon 6-Polypyrrole composite를 화학적으로 제조하였다. 이 복합재료의 표면과 체적전도도는 FeCl₃의 농도와 중합시간에 따라 10^-12-10^-3S/ cm의 범위를 나타내었다. 전류-전압특성과 전기전도도의 온도의존 성실험으로 부터 Nylon 6-Polypyrrole composites의 전도 mechanism은 주로 electronic conduction mechanism을 나타내었다. 이 composite film에 대하여 FT-IR spectrum분석과 광각 X-ray 산란 (wide angle X-ray scattering) 실험을 행하였으며, 광각 X-ray산란 실험으로 부터 이 복합재료의 결정구조는 큰 변화는 없었으나, pyrrole이 중합됨에 따라 Nylon 6의 α-type 결성의 형성이 억제되었다. 동력학적 성질 및 기계적 성질을 Rheovibron과 Instron으로 조사하였으며, 그 결과 이복합재료의 물성은 상당히 우수 하였다.

Highly conducting Nylon 6-Polypyrrole composites can be chemically obtained by exposing Nylon 6 films containing FeC1₃ to vapour of pyrrole. The surface and bulk conductivities of these composites were in the range of 10^-12-10^-3S/ cm depending on the concentration of FeCl³ and the polymerization time. From the current-voltage characteristics and temperature dependence of conductivities, we can conclude that the conduction mechanism of Nylon 6-Polypyrrole composites mainly depends on electronic conduction. These composite films were analysed by FT-IR spectroscopy and wide angle X-ray scattering(WAXS). From the WAXS study, there are no appreciable changes of the crystal structure of Nylon 6 composite films, but the formation of α-type crystal of Nylon 6 is suppressed during the polymerization of pyrrole. The dynamic and static mechanical properties were studied with Rheovibron and Instron, respectively. These composite films exhibited good mechanical properties.

[References]

Kaneto K, Yoshino K, Inuishi Y, Jpn. J. Appl. Phys., 21, L567 (1982)
Ohsawa T, Kaneto K, Yoshino K, Jpn. J. Appl. Phys., 23, L527 (1984)
Yoshino K, Kaneto K, Inoue S, Tsukagoshi K, Jpn. J. Appl. Phys., 22, L701 (1983)
Bjorklund R, Lundstrom I, J. Electron. Mat., 13, 211 (1984)
Audebert P, Bidan G, Synth. Met., 14, 71 (1986)
Ojio T, Miyata S, Polym. J., 18, 95 (1986)
Sugimoto R, Gu HB, Hayashi S, Yoshino K, Synth. Met., 18, 247 (1987)
Pron A, Kucharski Z, Budrowski C, Agorskaa MZ, Krichene S, Suwalski J, Dehe G, Lefrant S, J. Chem. Phys., 83, 5923 (1985)
Nakanishi K, Solomon PN, "Infrared Absorption Spectroscopy," Holden-Day, San Francisco (1977)
Pron A, Zagorska M, Fabianowski W, Polym. Commun., 28, 19 (1987)
Parker JP, Lindenmeyer PH, J. Phys. Sci., 21, 821 (1977)

[Referenced By]

[1] Kaneto K, Yoshino K, Inuishi Y, Jpn. J. Appl. Phys., 21, L567 (1982)

[2] Ohsawa T, Kaneto K, Yoshino K, Jpn. J. Appl. Phys., 23, L527 (1984)

[3] Yoshino K, Kaneto K, Inoue S, Tsukagoshi K, Jpn. J. Appl. Phys., 22, L701 (1983)

[4] Bjorklund R, Lundstrom I, J. Electron. Mat., 13, 211 (1984)

[5] Audebert P, Bidan G, Synth. Met., 14, 71 (1986)

[6] Ojio T, Miyata S, Polym. J., 18, 95 (1986)

[7] Sugimoto R, Gu HB, Hayashi S, Yoshino K, Synth. Met., 18, 247 (1987)

[8] Pron A, Kucharski Z, Budrowski C, Agorskaa MZ, Krichene S, Suwalski J, Dehe G, Lefrant S, J. Chem. Phys., 83, 5923 (1985)

[9] Nakanishi K, Solomon PN, "Infrared Absorption Spectroscopy," Holden-Day, San Francisco (1977)

[10] Pron A, Zagorska M, Fabianowski W, Polym. Commun., 28, 19 (1987)

[11] Parker JP, Lindenmeyer PH, J. Phys. Sci., 21, 821 (1977)