Electrochimica Acta, Vol.41, No.14, 2097-2105, 1996
Microscopic Description of the Electrode Surface and Double-Layer Capacity at the Electrode/Solution Interface
The analysis of the capacitance incorporating the variations with the surface charge density of the image plane position and of the metal/solvent distance of closest approach is discussed. The relation with other theoretical models and with some recent experimental studies of the electrode/solution interface is analysed. The proper interpretation of the semi-empirical contribution for the solvent obtained by correcting the inner-layer capacitance by a theoretical contribution associated with the metal non-ideality is emphasized. The use of this semi-empirical contribution for discussing solvent orientation (different solvent with same electrode and vice versa) is finally considered.
Keywords:IDEALLY POLARIZED ELECTRODE;X-RAY-REFLECTIVITY;DIFFERENTIAL CAPACITANCE;SOLVENT CONTRIBUTION;UNCHARGED ELECTRODE;WATER-MOLECULES;QUANTUM-THEORY;JELLIUM MODEL;METAL;DENSITY