Electrochimica Acta, Vol.42, No.5, 813-817, 1997
Some Peculiarities of Diffusion-Migration Ionic Transport in Electrochemical Systems Containing Fixed Charges
Theoretical analysis of mutual influence of diffusion-migration currents of cations of two different sorts is presented for the case when a system also contains immobile charged particles. It is shown that the partial limiting current of cations of the first sort increases with the increase of current of another sort of cations. The dependence of this correlation on the concentration of fixed charges is investigated.