Electrochimica Acta, Vol.43, No.1-2, 87-107, 1998
Characterizing electrochemical systems in the frequency domain
The use of various impedance spectroscopies, including electrochemical impedance spectroscopy (EIS), photoelectrochemical impedance spectroscopy (PEIS), and those defined using various electrochemical, hydrodynamical, and mechanical conjugate variables, for studying physico-electrochemical systems is briefly reviewed with emphasis on identifying and defining a common theoretical basis. In particular, we explore the concepts of "conjugate properties" and "reciprocity", the applicability of the Kramers-Kronig transforms, and the distinction between an impedance and a transfer function. We argue that the interpretation of impedance data in terms of electrical analogs and in terms of classical linear systems theory (I,ST) is possibly too restrictive, and that a more general basis is required to accommodate the broad range of "impedance spectroscopies" that are now being developed.
Keywords:KRAMERS-KRONIG TRANSFORMS;INTENSITY MODULATED PHOTOCURRENTS;QUARTZ-CRYSTAL MICROBALANCE;STATE PASSIVE FILMS;POINT-DEFECT MODEL;SEMICONDUCTOR ELECTRODES;STEADY-STATE;IMPEDANCE SPECTROSCOPY;SURFACE RECOMBINATION;ANODIC-DISSOLUTION