화학공학소재연구정보센터
Electrochemical and Solid State Letters, Vol.6, No.2, G19-G21, 2003
Properties of Mn-implanted BaTiO3, SrTiO3, and KTaO3
Mn ion implantation into single-crystal BaTiO3(K), SrTiO3, or KTaO3(Ca) was investigated for its effects on the magnetic properties of these materials. Following annealing at 700 degreesC, the Mn implantation was found to induce ferromagnetic behavior for most of the concentration range investigated. For BaTiO3, Mn implantation produced magnetic ordering temperatures near 300 K with coercivities less than or equal to 70 Oe. The magnetization/temperature plots showed a non-Brillouin-shaped curve. No secondary phases were detected by high resolution X-ray diffraction. The results are consistent with theoretical predictions for transition metal doping of BaTiO3. The same basic trends were observed for both SrTiO3 and KTaO3, with the exception that at high Mn concentrations (similar to5 atom %) the SrTiO3 was no longer ferromagnetic. (C) 2002 The Electrochemical Society.