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Electrochemical and Solid State Letters, Vol.7, No.12, G309-G312, 2004
Effects of high dose Ni, Fe, Co, and Mn implantation into SnO2
The effects of high dose (3 x 10(16) cm(-2)) implantation of Ni, Fe, Co, or Mn ions into bulk, single-crystal SnO2 substrates carried out at substrate temperature of similar to 350 degrees C to avoid amorphization of the implanted region on the magnetic properties of the material are reported. X-ray diffraction showed no evidence of secondary phase formation in the SnO2. The Mn-implanted samples remained paramagnetic, as also reported for samples doped during thin film growth, but the Fe, Co-, and Ni-implanted SnO2 showed evidence of hysteresis with approximate Curie temperatures of similar to 120 K (Co and Cr) or 300 K (Fe). The carrier density in the implanted region appears to be too low to support carrier-mediated origin of the ferromagnetism and formation of bound magnetic polarons may be one explanation for the observed magnetic properties. The much reduced Curie temperature seen in Co-implanted SnO2 compared to material doped during pulsed laser deposition suggests the residual implant damage degrades the magnetic properties. (C) 2004 The Electrochemical Society.