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Electrochemical and Solid State Letters, Vol.9, No.11, C181-C184, 2006
Long wavelength roughness optimization during thin Cu film electropolish
Recent studies of Cu electropolish indicate planarization is not possible due to a large diffusion layer thickness relative to a small post-electroplate step height and small Cu overburden available for electropolish. Assuming an integration scheme that includes a CMP step followed by electropolish, the subsequent challenge of maintaining surface roughness over 300 mu m range while electropolishing thin Cu films is addressed by optimizing applied current. For a typical electropolish solution of 6.4 M H3PO4, 5.4 M glycerin and 17.5 M H2O, an rms value of 38 angstrom, comparable to the incoming post-CMP wafers, is demonstrated for 2500 angstrom Cu removal. (c) 2006 The Electrochemical Society.