화학공학소재연구정보센터
Polymer(Korea), Vol.16, No.6, 638-645, November, 1992
폴리에틸렌/아이오노머 블렌드의 전기전도현상
Electrical Conduction of Polyethylene/Ionomer Blends
초록
두 종류의 PE/ionomer 블렌드, 즉 PE/Surlyn 1601 블렌드 및 PE/Surlyn 1652 블렌드의 전기전도 특성에 대하여 조사하였다. 조사결과. 두 블렌드의 전기전도기구는 동일하여 SCLC성 전도기구를 따른다는 사실을 알았다. 낮은 전기장에는 PE/Surlyn 1601 블렌드의 전류밀도가 상대적으로 큰 반면에 높은 전기장에서는 PE/Surlyn 1652 블렌드의 전류밀도가 상대적으로 큰 것으로 밝혀졌으며, PE/Surlyn 1601 블렌드의 경우 ionomer 함량이 증가함에 따라 높은 전기장에서 전류밀도가 낮아지는 현상이 발견되었는데, 이러한 현상을 유효전하이동도의 차이로서 설명하였다. 이 결과들은 PE/Surlyn 1601 블렌드에서는 전하가 트랩되는 경향이 강한 반면에 PE/Surlyn 1652 블렌드에서는 전하가 호핑에 의하여 전도되는 깅향이 강하다는 것을 의미하는데, 이는 ionomer에 있는 ionic cluster의 본질이 다르기 때문인 것으로 판단된다.
Electrical conduction characteristics of the PE/ionomer blends, i.e., PE/Surlyn 1652 blends and PE/Surlyn 1601 blends, have been investigated. It has been found that the SCLC mechanism works over the range of electric field of 10 to 400 kV/cm at several temperatures up to 100℃' for both blends. Higher conduction currents at low fields and lower conduction currents at high fields have been observed in PE/Surlyn 1601 blends than in PE/Surlyn 1652 blends. In the case of PE/Surlyn 1601 blends, conduction currents decrease as the Surlyn 1601 contents increase at high fields. The two features were explained in terms of the effective charge mobility. These observations indicate that the charges tend to be trapped in PE/Surlyn 1601 blends and conducted by a hopping mechanism in PE/Surlyn 1652 blends, which can be attributed to the differences in the nature of ionic clusters in both ionomers.
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