Schiff 염기를 갖는 선형 8-배위 지르코늄(Ⅳ)중합체

장주환; 김학진; 박근수; 최원종

Polymer(Korea), Vol.17, No.3, 316-323, May, 1993

Export Citation

Schiff 염기를 갖는 선형 8-배위 지르코늄(Ⅳ)중합체

Linear Zr(Ⅳ) Eight-Coordinate Polymer with Schiff-Base

장주환, 김학진, 박근수, 최원종

초록

지르코늄(Ⅳ) 이소프로폭시드 이소프로판올 착물에 2-메르캅토피리미딘(MPD)과 살리실알데히드(SA)을 반응(몰비=1:2:2)시켜 8-배위 지르코늄(Ⅳ) 착물을 합성하였다. 합성한 8-배위 지르코늄(Ⅳ) 착물에 1,4-디아미노벤젠(DAB)을 축합반응시켜 Schiff 염기를 갖는 새로운 선형 8-배위 지르코늄(Ⅳ) 중합체를 얻었다. 착물과 중합체의 구조를 핵 자기 공명 분광기, 적외선 분광기, 질량분석기 및 원소분석으로 확인하였으며, 중합체의 용해도, 점도 및 열적특성을 조사하였다.

The eight-coordinate zirconium(IV) complex has been synthesized from the salicylaldehyde(SA), 2-mercaptopyrimidine(MPD) and zirconium(Ⅳ) isopropoxide isopropanol complex at a mole ratio of 2:2:1, respectively. A new linear eight-coordinated Zr(Ⅳ) polymer with Schiff-base was prepared by condensation polymerization of eight-coordinated Zr(Ⅳ) complex and 1,4-diaminobenzone(DAB). Structure of the complex was determined by NMR, IR, mass spectrometry and elemental analysis. Solubilities, viscosities and thermal stabilities to the polymer has been investigated.

[References]

Carrahar C, J. Chem. Educ., 58, 921 (1981)
Holliday L, Inorg. Macromol. Rev., 1, 3 (1970)
Holliday L, subsequent papers in the volume dated 1970-1972
Natanson EM, Bryk MT, Russ. Chem. Rev., 41, 671 (1972)
Brown SB, Dewar MJS, Inorg. Chim. Acta, 34, 221 (1979)
Wrobleski JT, Brown DB, Inorg. Chem., 18, 2734 (1979)
Davison JB, Wynne KJ, Macromolecules, 11, 186 (1978)
vanKrevelen DW, Chem. Ind., 49, 1396 (1971)
vanKrevelen DW, Text. Prog., 8(124-125), 156 (1976)
Block BP, Gillman HD, Nannelli P, "The Synthesis and Characterization of the Poly(Metal Phosphinates)," ONR Contract N00014-69-C-0122, Final Report, June, P2 (1977)
Archer RD, Batschelet WH, Illingsworth ML, J. Macromol. Sci.-Chem., A16(1), 216 (1981)
Archer RD, Illingsworth NL, Rau DN, Hardiman CJ, Macromolecules, 18, 7 (1985)
Illingsworth ML, Rheingold AL, Inorg. Chem., 26, 4312 (1987)
Archer RD, Wang B, Inorg. Chem., 29, 39 (1990)
Corey EJ, Suggs JW, Tetrahedron Lett., 2647 (1975)
Perrin DD, Armarego WLF, Perrin DR, "Purification of Laboratory Chemicals," 3rd Ed. (1988)
Marini PJ, Murray KS, West BO, J. Chem. Soc.-Dalton Trans., 143 (1983)
Kasmai GW, Villascusa FW, Wollner TE, Synthesis, 763 (1989)
Archer RD, Tong W, Inorg. Chem., 31, 3332 (1992)

[1] Carrahar C, J. Chem. Educ., 58, 921 (1981)

[2] Holliday L, Inorg. Macromol. Rev., 1, 3 (1970)

[3] Holliday L, subsequent papers in the volume dated 1970-1972

[4] Natanson EM, Bryk MT, Russ. Chem. Rev., 41, 671 (1972)

[5] Brown SB, Dewar MJS, Inorg. Chim. Acta, 34, 221 (1979)

[6] Wrobleski JT, Brown DB, Inorg. Chem., 18, 2734 (1979)

[7] Davison JB, Wynne KJ, Macromolecules, 11, 186 (1978)

[8] vanKrevelen DW, Chem. Ind., 49, 1396 (1971)

[9] vanKrevelen DW, Text. Prog., 8(124-125), 156 (1976)

[10] Block BP, Gillman HD, Nannelli P, "The Synthesis and Characterization of the Poly(Metal Phosphinates)," ONR Contract N00014-69-C-0122, Final Report, June, P2 (1977)

[11] Archer RD, Batschelet WH, Illingsworth ML, J. Macromol. Sci.-Chem., A16(1), 216 (1981)

[12] Archer RD, Illingsworth NL, Rau DN, Hardiman CJ, Macromolecules, 18, 7 (1985)

[13] Illingsworth ML, Rheingold AL, Inorg. Chem., 26, 4312 (1987)

[14] Archer RD, Wang B, Inorg. Chem., 29, 39 (1990)

[15] Corey EJ, Suggs JW, Tetrahedron Lett., 2647 (1975)

[16] Perrin DD, Armarego WLF, Perrin DR, "Purification of Laboratory Chemicals," 3rd Ed. (1988)

[17] Marini PJ, Murray KS, West BO, J. Chem. Soc.-Dalton Trans., 143 (1983)

[18] Kasmai GW, Villascusa FW, Wollner TE, Synthesis, 763 (1989)

[19] Archer RD, Tong W, Inorg. Chem., 31, 3332 (1992)