This paper is a continuation of the discussion of N2O formation during char combustion started in a previous paper (Energy Fuels 1995, 9, 10-19). The effect bf different NO and CO concentrations in the inlet gas, as well as the effect of changing gas residence time within the fixed bed and after the fixed bed on the emission of N2O from char particles burning at single particle conditions, is reported. In order to distinguish between char nitrogen and NO from the inlet gas a N-15-isotope-marked NO was used in the inlet gas. The experiments were carried out in a fixed bed reactor containing quartz sand (SiO2) to support the coal particles. The bituminous coal particles were devolatilized in situ prior to the actual combustion in an argon flow. The inlet gas mixture contained (NO)-N-15, CO, O-2, and Ar or just (NO)-N-15, O-2, and Ar. The (NO)-N-15 concentration was varied between 500 and 1950 ppm, and the CO concentration was varied between 0 and 2500 ppm. The inlet gas flow was varied between 297 and 1200 mL/min NTP (273 K, 1 atm). The bed temperature was 1073 K. The off-gases were analyzed for N2O. The addition of (NO)-N-15 to the inlet gas led to the formation of (NNO)-N-15-N-14 and (N2O)-N-15, and the formation of these species increased with increasing concentration of (NO)-N-15 in the inlet gas, especially the formation of (N2O)-N-15. The formation of (NNO)-N-15-N-14 was greater than the formation of (N2O)-N-15 under all circumstances examined, but with increasing (NO)-N-15 concentration in the inlet gas the (N2O)-N-15 formation increased, and was almost as great as the formation of (NNO)-N-15-N-14. The influence of gas residence time within the fixed bed and after the fixed bed was confirmed, and the N2O formation and formation of (NNO)-N-15-N-14 and (N2O)-N-15 increased substantially with increasing gas residence time. The addition of CO to the inlet gas had almost no effect on the N2O formation.