유기 건축 복합재용 불포화폴리에스테르/알루미나 복합재료의 물성향상 : (Ⅱ) 매트릭스 수지의 종류에 따른 고찰

최철림; 장정식

Polymer(Korea), Vol.18, No.1, 86-92, January, 1994

Performance Improvement of Unsaturated Polyester/Alumina Composites for Organic Building Material : (Ⅱ) Mechanical Properties of Different Matrix Resins

최철림, 장정식

초록

불포화 폴리에스테르/알루미나 복합재료의 기계적 물성을 증진시킬 목적으로, 서로 다른 매트릭스를 이용하여 복합재료를 제조하였다. 충전제인 알루미나의 표면은 개질화한 불포화 폴리에스테르/알루미나 복합재료의 경우, 굴곡 물성의 최대값은 실란 농도가 0.50wt%일 때였으며, 매트릭스 종류에는 무관하였다. 불포화 폴리에스테르/알루미나 복합재료의 인장 물성은 isophthalic계가 가장 우수하였으며, bisphenol A계가 가장 낮은 물성을 나타내었다. 또한 실란 카플링제로 알루미나 표면을 개질화하였을 때 복합재료의 기계적 물성과 복합재료 계면 개질화와의 상관관계도 함에 고찰하였다.

In order to improve the mechanical properties of unsaturated polyester/alumina composite, polymer composites were fabricated using different matrix resins. In the case of surface treated alumina/unsaturated polyester composite, maximum flexural properties were observed in the composite prepared from the alumina treated with silane coupling agents of 0.50 wt%, irrespective of the types of matrix resins. Isophthalic polyester composite show the highest tensile properties and bisphenol A polyester composites have the lowest tensile properties among the unsaturated polyester composites studied. In addition, the relationship between the mechanical properties of silane treated alumina/unsaturated polyester composites and interfacial modification were also discussed.

[References]

Dudgeon CD, "Unsaturated Polyesters," Engineering Materials Handbook, Vol. 2, Engineering Plastics, ASM International, pp. 246-251 (1988)
Dudgeon CD, "Unsaturated Polyesters," Engineering Materials Handbook, Vol. 1, Composites, ASM International, pp. 91-96 (1987)
Smith PL, Comstock LR, "Polyester Compositions," U.S. Patent, 3,549,586 (1970)
Comstock LR, Smith PL, "Unsaturated polyester Compositions," U.S. Patent, 3,718,714 (1973)
Comstock LR, Smith PL, "Unsaturated Polyester Compositions," U.S. Patent, 4,284,736 (1981)
Hupp SS, "Engineering Aspects of the SMC Process," Proceedings of the 42th Annual Conference, Composites Institute, The Society of the Plastics Industry, Inc. 11-E (1987)
Anderson DH, Lancsettle GA, "Witchcraft and Wizardry in Composite Molding," ADvanced Composites Conference Proceedings, pp. 139-145 (1985)
Knoebel DS, "Mechanical Property and Performance Characterizationof Marine Laminates and the Effect of Matrix Resins," Proceedingsof the 40th Annual Conference, Composites Institute, The Society of the Plastics Industry, Inc. 12-C (1985)
Dudgeon CD, "Overview of Unsaturated Polyester Resins," Proceedings of the 34th International SAMPE Symposium, pp. 2333-2345 (1989)
Mutch W, Plast. World, 45, 31 (1987)
Shirayama K, Mater. Struct., 19, 249 (1986)
Powell D, "Encyclopedia of Polymer Science and Engineering," pp. 146-147, Vol. 4, 2nd Ed., John Wiley and Sons, Inc., New York (1986)
Feldman D, "Polymeric Building Materials," Elsevier Applied Science, London (1989)
Dudgeon CC, Proceeding of 34th International SAMPE Symposium, 2333 (1989)
Updegraff IH, "Handbook of Composites," G. Lubin Ed., Van Nostrand Reinhold, Inc., New York (1982)
Thomas LL, "SPI Plastic Engineering Handbook," Van Nostrand Reinhold, Inc., New York (1990)
Ng H, Manas-Zloczower I, Polym. Eng. Sci., 29, 1097 (1989)
Yang YS, Lee LJ, J. Appl. Polym. Sci., 37, 313 (1983)
Jelcic Z, Ranogajec F, Polym. Compos., 12, 384 (1991)
Lee D, Han CD, J. Appl. Polym. Sci., 34, 1235 (1987)
Muzumdar SV, Lee LJ, Polym. Eng. Sci., 31, 1547 (1991)
Dharmarajan N, Vipulanandan C, J. Appl. Polym. Sci., 42, 601 (1991)
Yang YS, Lee LJ, Polymer, 29, 1793 (1988)
Hand CD, Lee D, J. Appl. Polym. Sci., 33, 2859 (1987)

[Referenced By]

[1] Dudgeon CD, "Unsaturated Polyesters," Engineering Materials Handbook, Vol. 2, Engineering Plastics, ASM International, pp. 246-251 (1988)

[2] Dudgeon CD, "Unsaturated Polyesters," Engineering Materials Handbook, Vol. 1, Composites, ASM International, pp. 91-96 (1987)

[3] Smith PL, Comstock LR, "Polyester Compositions," U.S. Patent, 3,549,586 (1970)

[4] Comstock LR, Smith PL, "Unsaturated polyester Compositions," U.S. Patent, 3,718,714 (1973)

[5] Comstock LR, Smith PL, "Unsaturated Polyester Compositions," U.S. Patent, 4,284,736 (1981)

[6] Hupp SS, "Engineering Aspects of the SMC Process," Proceedings of the 42th Annual Conference, Composites Institute, The Society of the Plastics Industry, Inc. 11-E (1987)

[7] Anderson DH, Lancsettle GA, "Witchcraft and Wizardry in Composite Molding," ADvanced Composites Conference Proceedings, pp. 139-145 (1985)

[8] Knoebel DS, "Mechanical Property and Performance Characterizationof Marine Laminates and the Effect of Matrix Resins," Proceedingsof the 40th Annual Conference, Composites Institute, The Society of the Plastics Industry, Inc. 12-C (1985)

[9] Dudgeon CD, "Overview of Unsaturated Polyester Resins," Proceedings of the 34th International SAMPE Symposium, pp. 2333-2345 (1989)

[10] Mutch W, Plast. World, 45, 31 (1987)

[11] Shirayama K, Mater. Struct., 19, 249 (1986)

[12] Powell D, "Encyclopedia of Polymer Science and Engineering," pp. 146-147, Vol. 4, 2nd Ed., John Wiley and Sons, Inc., New York (1986)

[13] Feldman D, "Polymeric Building Materials," Elsevier Applied Science, London (1989)

[14] Dudgeon CC, Proceeding of 34th International SAMPE Symposium, 2333 (1989)

[15] Updegraff IH, "Handbook of Composites," G. Lubin Ed., Van Nostrand Reinhold, Inc., New York (1982)

[16] Thomas LL, "SPI Plastic Engineering Handbook," Van Nostrand Reinhold, Inc., New York (1990)

[17] Ng H, Manas-Zloczower I, Polym. Eng. Sci., 29, 1097 (1989)

[18] Yang YS, Lee LJ, J. Appl. Polym. Sci., 37, 313 (1983)

[19] Jelcic Z, Ranogajec F, Polym. Compos., 12, 384 (1991)

[20] Lee D, Han CD, J. Appl. Polym. Sci., 34, 1235 (1987)

[21] Muzumdar SV, Lee LJ, Polym. Eng. Sci., 31, 1547 (1991)

[22] Dharmarajan N, Vipulanandan C, J. Appl. Polym. Sci., 42, 601 (1991)

[23] Yang YS, Lee LJ, Polymer, 29, 1793 (1988)

[24] Hand CD, Lee D, J. Appl. Polym. Sci., 33, 2859 (1987)