ABS/Phenoxy 용융블렌드

최치훈; 이수민; 김병규

Polymer(Korea), Vol.18, No.2, 166-171, March, 1994

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ABS/Phenoxy 용융블렌드

Melt Blends of ABS with Phenoxy

최치훈, 이수민, 김병규

초록

ABS/phenoxy 용융블렌드를 전 조성에 걸쳐 제조하였으며, 주사전자현미경 관찰을 통해 이들 블렌드가 전형적인 비상용계 블렌드의 상분리 구조를 취하고 있음을 확인하였다. 블렌드에서 SAN의 T_g는 거의 일정하였으나 phenoxy의 T_g는 5∼8℃ 정도 증가하였다. ABS-rich 블렌드에서 인장물성(탄성률, 강도)은 혼합법칙 이상으로 향상되었으나 파단전율 및 내충격성은 현저히 감소하였으며 이러한 현상을 고무입자의 phenoxy상으로의 이동에 기인한 것으로 해석하였다. 용융점도는 ABS-rich 블렌드에서 약간의 항복거동을 보였으나 phenoxy함량 증가와 더불어 조성에 따라 일률적인 감소를 보였다.

ABS/phenoxy blends were prepared over the whole range of composition using a Brabender Plasticorder. Scanning electron micrographs(SEM) showed a typical two phase morphology. Glass transition temperature(T_g) of SAN was almost unchanged in the blends, while T_g of phenoxy increased by 5∼8℃ in the blends. Synergistic effect of tensile modulus and strength were noted in ARS-rich blends, Where a drastic drop of ductility was seen, and the results were interpreted in terms of rubber particle migration into phenoxy phase. Melt viscosity showed yield in ABS-rich blends, and monotonically deceased with increasing Phenoxy content.

[References]

Encyclopedia of Polymer Science and Engineering, J.I. Kroschwitz, H.F. Mark, N.M. Bikales, C.G. Overberger, and G. Menges eds., Vol. 2, Wiley Interscience, New York (1985)
Brydson JA, "Plastics Materials," 4th Ed., Butterworth Scientific, London (1982)
Bucknall CB, "Toughened Plastics," Applied Science, London (1977)
Kim JH, Keskkula H, Paul DR, J. Appl. Polym. Sci., 40, 183 (1990)
Kim BK, Shin GS, J. Appl. Polym. Sci., 48, 945 (1993)
Aoki Y, Macromolecules, 20, 2208 (1987)
Aoki Y, Nukayama K, J. Soc. Rheo. Jpn., 9, 39 (1981)
Aoki Y, Watanabe M, Polym. Eng. Sci., 32(13), 878 (1992)
Martinez JM, Eguiazabal JI, Nazabal J, J. Macromol. Sci.-Phys., B30(4), 345 (1984)
Robeson LM, Furtek B, J. Appl. Polym. Sci., 23, 645 (1979)
Defieuw G, Groeninkx G, Reynaers H, Polymer, 30, 2164 (1989)
Iriarte M, Espi E, Etxeberria A, Valero M, Fernandez-Berridi MJ, Iruin JJ, Macromolecules, 24, 5546 (1991)
Kolarik J, Lednicky F, Polym. Eng. Sci., 32, 886 (1992)
Kim WN, Burns CM, J. Appl. Polym. Sci., 41, 1575 (1990)
Suess M, Kressler J, Kammer HW, Polymer, 28, 957 (1987)
Kim YJ, Shin GS, Lee IT, Kim BK, J. Appl. Polym. Sci., 47, 295 (1993)
Kim BK, Lee YM, Jeong HM, Polymer, 34(10), 2075 (1993)
Ahn TO, Kim CK, Kim BK, Jeong HM, Huh JD, Polym. Eng. Sci., 30(6), 341 (1990)
Kim BK, Shin GS, Kim YJ, Park TS, J. Appl. Polym. Sci., 47, 1581 (1993)
Barlow JW, Paul DR, Polym. Eng. Sci., 24, 525 (1984)
Lee SM, Choi CH, Kim BK, Eur. Polym. J., accepted
Elmendrop JJ, VanderVegt AK, "Two Phase Polymer System," L.A. Utracki ed., Oxford University Press, New York (1991)

[1] Encyclopedia of Polymer Science and Engineering, J.I. Kroschwitz, H.F. Mark, N.M. Bikales, C.G. Overberger, and G. Menges eds., Vol. 2, Wiley Interscience, New York (1985)

[2] Brydson JA, "Plastics Materials," 4th Ed., Butterworth Scientific, London (1982)

[3] Bucknall CB, "Toughened Plastics," Applied Science, London (1977)

[4] Kim JH, Keskkula H, Paul DR, J. Appl. Polym. Sci., 40, 183 (1990)

[5] Kim BK, Shin GS, J. Appl. Polym. Sci., 48, 945 (1993)

[6] Aoki Y, Macromolecules, 20, 2208 (1987)

[7] Aoki Y, Nukayama K, J. Soc. Rheo. Jpn., 9, 39 (1981)

[8] Aoki Y, Watanabe M, Polym. Eng. Sci., 32(13), 878 (1992)

[9] Martinez JM, Eguiazabal JI, Nazabal J, J. Macromol. Sci.-Phys., B30(4), 345 (1984)

[10] Robeson LM, Furtek B, J. Appl. Polym. Sci., 23, 645 (1979)

[11] Defieuw G, Groeninkx G, Reynaers H, Polymer, 30, 2164 (1989)

[12] Iriarte M, Espi E, Etxeberria A, Valero M, Fernandez-Berridi MJ, Iruin JJ, Macromolecules, 24, 5546 (1991)

[13] Kolarik J, Lednicky F, Polym. Eng. Sci., 32, 886 (1992)

[14] Kim WN, Burns CM, J. Appl. Polym. Sci., 41, 1575 (1990)

[15] Suess M, Kressler J, Kammer HW, Polymer, 28, 957 (1987)

[16] Kim YJ, Shin GS, Lee IT, Kim BK, J. Appl. Polym. Sci., 47, 295 (1993)

[17] Kim BK, Lee YM, Jeong HM, Polymer, 34(10), 2075 (1993)

[18] Ahn TO, Kim CK, Kim BK, Jeong HM, Huh JD, Polym. Eng. Sci., 30(6), 341 (1990)

[19] Kim BK, Shin GS, Kim YJ, Park TS, J. Appl. Polym. Sci., 47, 1581 (1993)

[20] Barlow JW, Paul DR, Polym. Eng. Sci., 24, 525 (1984)

[21] Lee SM, Choi CH, Kim BK, Eur. Polym. J., accepted

[22] Elmendrop JJ, VanderVegt AK, "Two Phase Polymer System," L.A. Utracki ed., Oxford University Press, New York (1991)