Transesterification of alpha-haloesters and beta-ketoesters over Mg-Al-hydrotalcites (HT)-like anionic clays

Bulbule VJ; Borate HB; Munot YS; Deshpande VH; Sawargave SP; Gaikwad AG

Journal of Molecular Catalysis A-Chemical, Vol.276, No.1-2, 158-161, 2007

DOI10.1016/j.molcata.2007.07.006 Export Citation

Transesterification of alpha-haloesters and beta-ketoesters over Mg-Al-hydrotalcites (HT)-like anionic clays

Bulbule VJ, Borate HB, Munot YS, Deshpande VH, Sawargave SP, Gaikwad AG

Transesterification of alpha-haloesters was achieved by reaction of alcohols in the presence of Mg-Al-HT-like anionic clays. beta-Ketoesters were also transesterified under similar conditions on reaction with alcohols with a wide variety of functional groups. (c) 2007 Elsevier B.V. All rights reserved.

Keywords:transesterification;alpha-haloesters;beta-ketoesters;hydrotalcites;heterogeneous catalyst