Journal of Colloid and Interface Science, Vol.313, No.1, 41-52, 2007
Capillary condensation in pores with rough walls: A density functional approach
The effect of surface roughness of slit-like pore walls on the capillary condensation of a spherical particles and short chains is studied. The gas molecules interact with the substrate by a Lennard-Jones (9, 3) potential. The rough layer at each pore wall has a variable thickness and density and consists of a disordered quenched matrix of spherical particles. The system is described in the framework of a density functional approach and using computer simulations. The contribution due to attractive van der Waals interactions between adsorbate molecules is described by using first-order mean spherical approximation and mean-field approximation. (c) 2007 Elsevier Inc. All rights reserved.