The present paper involves a metal/polymer joint in a tailcone in a kinetic energy penetrator (KEP), one of the ammunition types used by the military. It is currently made of aluminum 7075 alloy, which could be partly replaced by long fiber thermoplastic (LFT) composite. Two different types of aluminum insert geometries were considered, viz., beaded and threaded. Thermal stresses set in during cooling of the tailcone from the processing temperature mainly because of the difference in the values of coefficients of thermal expansion and differential cooling between the aluminum and the LFT composite. Finite element (FE) modeling was done to predict the temperature profile during the cooling of the tailcone from the processing temperature. FE results showed that the LFT composite part of the tailcone cooled faster than the aluminum insert. Experimental verification of this temperature profile was obtained by infrared (IR) thermography. Based on the temperature profile, thermal stresses at the metal/LFT composite interface were estimated using an FE model. Different magnitudes of thermal stresses were present at the aluminum/LFT composite interface owing to the nature of distribution of fibers around the insert. Magnitude of thermal stresses in the case of a beaded insert was approximately 2.5 MPa whereas in the case of a threaded insert, it was approximately 12 MPa.