Journal of Chemical Thermodynamics, Vol.39, No.10, 1399-1403, 2007
Analysis of the thermodynamic properties of (1-chloroalkane+1-alkanol) mixtures using the Nitta-Chao group contribution model
The interaction parameters between group chloro (-Cl) and hydroxyl (-OH) for the group contribution model of Nitta et al. 1977 (Nitta-Chao model) have been estimated with the use of a data base of experimental thermodynamic properties. The results obtained by the Nitta-Chao model with these new parameters were compared with predictions by other models such as UNIFAC model (versions of Dang and Tassios 1986, Larsen et al. 1987 and Gmehling et al. 1993). (c) 2007 Elsevier Ltd. All rights reserved.