Chemical Physics Letters, Vol.442, No.4-6, 478-482, 2007
Single-scan 2D NMR spectroscopy on a 25 T bitter magnet
2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multi-scan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D 'ultrafast' acquisition schemes, which correlate interactions along all spectral dimensions within a single-scan. (c) 2007 Published by Elsevier B.V.