The topological polyrotaxane was built from an ammonium salt as an axle component bearing one olefin and one bulky unit at the end of chain and the derivative of dibenzo-24-crown-8 (DB24C8) as a wheel component having one terminal olefin. In this system, two kinds of reactions work at the same time as a driving force of the polymer construction. One is the inclusion reaction between the ammonium salt part of axle and the wheel, another is metathesis reaction between olefins of the axle and olefins of the wheel.