The novel porphyrins 5,10,15,20-tetra-[4-(3-phenoxy)-propoxy]phenyl porphyrin, H(2)Pp(a) and 5,10,15,20-tetra-[2-(3-phenoxy)-propoxy]phenyl porphyrin, H(2)Pp(b) and their corresponding copper(H) complexes CuPp(a), CuPp(b) were synthesized and characterized by using various spectroscopic techniques. The photocatalytic activity of polycrystalline TiO2, samples impregnated with H(2)Pp(a), H(2)Pp(b), CuPp(a) and CuPp(b) as sensitizers have been investigated by carrying out the photo-degradation of 4-nitrophenol (4-NP) as a probe reaction in aqueous suspension and under visible light. The maximum photocatalytic activity was obtained using TiO2 loaded with a monolayer of the copper porphyrin CuPp(b) in the amount of 18 mu mol per gram of TiO2. The photocatalytic efficiency decreased in the following order: TiO2-CuPp(b), TiO2-CuPp(a), TiO2-H(2)Pp(b), TiO2-H(2)Pp(a). A possible mechanism of the photocatalytic degradation is also proposed. (C) 2007 Elsevier B.V. All rights reserved.