To tailor the interaction across composite interfaces especially for the development of green composites, i.e. composites made completely from renewable materials, information about the fibre surfaces is required. We review the current state of the art of methods to determine the surface tension of natural fibres and discuss the advantages and disadvantages of techniques used. Although numerous techniques have been employed to characterise surface tension of natural fibres, it seems that commonly used wetting techniques are very much more affected by the non-ideal character of natural fibres. Inverse Gas Chromatography (IGC) is a much better suited technique to determine the surface energetic properties of natural fibres than wetting techniques. The surface tension of natural reinforcements, determined using IGC, was reported for nanosized bacterial cellulose as well as bamboo, cornhusk, flax, hemp and sisal, covering a wide range of cellulose content. The effect of methods to separate/extract fibres from the plants as well as of a few surface modification procedures on the fibre surface properties is also reviewed. The dispersive part of the natural fibre surface tension gamma(d)(s) varies from 32 to 61 mJ/m(2). The fibre surface tension increases with increasing cellulose content of natural fibres. We also found that a higher basicity (Donor Number, K-B to Acceptor Number, K-A ratio) was observed for fibres containing more cellulose. This may be reflective of higher crystalline cellulose content in the surfaces of the fibres, as only the ether linkage of the cellulose is labile for hydrogen bonding.