Polysilanes with an optically active alkoxy group, i.e., (S)-(+)-2-butoxy, (R)-(-)- 2-butoxy, ( S)-(-)- 2-methyl-1-butoxy, and ( S)-(+)-3,7-dimethyl-1-octoxy, at the terminal positions, the chiral carbon centers of which were located at the a, beta, and. positions relative to the oxygen, respectively, were prepared, and the effect of the position of chiral center of the terminal optically active group on the induction of optical activity in polysilanes was investigated. The circular dichroism ( CD) spectra of these polymers showed positive Cotton signals around 340 nm at temperatures below - 20 degrees C, but the intensities were small, indicating that the optically active groups at the terminal positions have some ability, albeit small, to induce optical activity to the polysilanes. Further, the optically active ( S)-(+)-2-butoxy and ( R)-(-)-2-butoxy groups did not control the helical sense direction of the polymers, despite the different chiral stimuli from the 2-butoxy groups introduced to the terminal positions. To control the helical structure of polysilanes by the use of optically active terminal groups, appropriate optically active groups are required.