The use of exergy is described as a measure for identifying and explaining the benefits of sustainable energy and technologies, so the benefits can be clearly understood and appreciated by experts and non-experts alike, and the utilization of sustainable energy and technologies can be increased. Exergy can be used to assess and improve energy systems, and can help better understand the benefits of utilizing green energy by providing more useful and meaningful information than energy provides. Exergy clearly identifies efficiency improvements and reductions in thermodynamic losses attributable to more sustainable technologies. A new sustainability index is developed as a measure of how exergy efficiency affects sustainable development. Exergy can also identify better than energy the environmental benefits and economics of energy technologies. The results suggest that exergy should be utilized by engineers and scientists, as well as decision and policy makers, involved in green energy and technologies in tandem with other objectives and constraints. (c) 2007 Elsevier Ltd. All rights reserved.