Industrial & Engineering Chemistry Research, Vol.46, No.23, 7598-7604, 2007
Kinetic Modeling of photocatalyzed soot oxidation on titanium dioxide thin films
Recent research [Mills et al. Chemosphere 2006, 64, 1032-1035; Lee and Choi J. Phys. Chem. B 2002, 106, 11818-11822] has demonstrated photocatalytic oxidation of "soot" by titanium dioxide thin films. However, little attention has been paid to developing kinetic models of photocatalyzed soot destruction. We develop here a series/parallel kinetic model for soot oxidation and use it to analyze the CO2 data of Mills et al. and the mass loss data of Lee and Choi. The model assumes two oxidation pathways: a single step yielding CO2 directly and a serial sequence through a solid intermediate species, which is subsequently oxidized to CO2. We extend this simple model to include variable O-2 partial pressure, which is used to evaluate the initial CO2 data of Lee and Choi. These models fit the experimental CO2 data of Mills et al. and Lee and Choi well. The simple kinetic model also describes the mass loss data of Lee and Choi for the front mode of sample irradiation.