In this study the tracking problem for a class of non-linear uncertain systems is analyzed. The considered class of non-linear systems are restricted by those verifying the global Lipschitz condition on non-linearities making them linear-like. A new sliding mode neurocontroller is suggested to solve this problem. The controller desing includes the on-line state estimates construction and the corresponding tracking control based on sliding mode approach and the reconstructed dynamics generated by a special non-linear observer. A special sliding mode technique during the "off-line training" to estimate the right-hand side of the given dynamics in finite-time was applied. This procedure allows use of these estimates for the best (in LQ-sense) nominal weights selection in the neuro observer designed. A switching (sign) type term is incorporated in the observer structure to correct the current state estimates using just the on-line measurable output. This observer is supplied with a new learning procedure with switching structure. Two illustrative examples are presented: a benchmark problem related with a nominal linear system and a real chemical procedure dealing with the organic compounds elimination by ozone effect.