Korean Journal of Chemical Engineering, Vol.25, No.3, 471-473, May, 2008
Catalytic performance of pyridinium salt ionic liquid in the synthesis of cyclic carbonate from carbon dioxide and butyl glycidyl ether
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The catalytic performance of pyridinium salt ionic liquids in the reaction of butyl glycidyl ether and carbon dioxide was investigated in this study. The catalytic activity was studied in a batch reactor with different 1-alkylpyridinium salt ionic liquids at 60-140 ℃. The conversion of butyl glycidyl ether was affected by the structure of the ionic liquid; the one with the cation of bulkier alkyl chain length showed better reactivity. The effect of carbon dioxide pressure, reaction temperature and zinc bromide co-catalyst on this reaction was also discussed.
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