Dye adsorption characteristics of alginate/polyaspartate hydrogels

Young Sil Jeon; Jing Lei; Ji-Heung Kim

Journal of Industrial and Engineering Chemistry, Vol.14, No.6, 726-731, November, 2008

DOI10.1016/j.jiec.2008.07.007 Export Citation

Dye adsorption characteristics of alginate/polyaspartate hydrogels

Young Sil Jeon, Jing Lei, and Ji-Heung Kim^†

Department of Chemical Engineering, Polymer Technology Institute Sungkyunkwan University Suwon, Kyonggi 440-746, Republic of Korea

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This study examined the removal of some basic dyes, such as Methylene Blue, Malachite Green and Methyl Orange, using alginate or alginate/polyaspartate composite gel beads. The adsorption of dyes from aqueous solutions at 25 ℃ was examined using a batch sorption technique. The effects of CaCl2 and the dye concentration on the adsorption were examined. Type-S adsorption isotherms were obtained, which is characteristic of a weak solute-solid interaction. The ionic interaction between the dye molecule and gel matrix appears to be responsible for the efficient adsorption of cationic dyes in this system. These results suggest that an alginate/polyaspartate gel can be used as an effective sorbent for water pollutants such as dyes, and the immobilization of these organic contaminants in the hydrogels from wastewater can solve one of the most important environmental problems in the related industry.

Keywords:Hydrogel;Dye adsorption;Polyaspartate;Alginate;Cationic dyes

[References]

Wang S, Boyjoo Y, Choueib A, Zhu ZH, Water Research, 39, 129 (2005)
Saraydin D, Karadag E, Guven O, J. Appl. Polym. Sci., 79(10), 1809 (2001)
Jeon CH, Makhaeva EE, Khokhlov AR, J. Polym. Sci. B: Polym. Phys., 37(12), 1209 (1999)
Saha B, Streat M, Ind. Eng. Chem. Res., 44(23), 8671 (2005)
Hashem A, Socker HH, Abdel Halim ES, Gamal A, Adsorpt. Sci. Technol., 23, 455 (2005)
Delval F, Crini G, Bertini S, Filiatre C, Torri G, Carbohydr. Polym., 60, 67 (2005)
Essawy HA, Ibrahim HS, React. Funct. Polym., 61, 421 (2004)
Omidian H, Rocca JG, Park K, J. Control. Release, 102, 3 (2005)
Griffith LG, Acta Mater., 48, 263 (2000)
Shin J, Lim YM, Jeun JP, Nho YC, J. Ind. Eng. Chem., 13(6), 997 (2007)
Kim KS, Vincent B, Cosgrove T, J. Ind. Eng. Chem., 12(1), 91 (2006)
El-Hag Ali A, Shawky HA, Abd El Rehim HA, Hegazy EA, Eur. Polym. J., 39, 2337 (2003)
Kang HW, Tabata Y, Ikada Y, Biomaterials, 20, 1339 (1999)
You SJ, Ahn WS, Jang HS, Kang MI, Chun HJ, Lim YM, Nho YC, J. Ind. Eng. Chem., 13(1), 116 (2007)
Sarmento B, Martins S, Ribeiro A, Veiga F, Neufeld R, Ferreira D, Int. J. Pept. Res. Ther., 12, 131 (2006)
Wolk SK, Swift G, Paik YH, Yocom KM, Smith RL, Simon ES, Macromolecules, 27(26), 7613 (1994)
Nakato T, Yoshitake M, Matsubara K, Tomida M, Kakuchi T, Macromolecules, 31(7), 2107 (1998)
Neri P, Antoni G, Benvenuti F, Colola F, Gazzei G, J. Med. Chem., 16, 893 (1972)
Kim JH, Lee JH, Yoon SW, J. Ind. Eng. Chem., 8(2), 138 (2002)
Min SK, Kim SH, Kim JH, J. Ind. Eng. Chem., 6(4), 276 (2000)
Yang J, Fang L, Tan TW, J. Appl. Polym. Sci., 102(1), 550 (2006)
Sahiner N, Saraydin D, Karadag E, Guven O, Polym. Bull., 41(3), 371 (1998)
dos Anjos FSC, Vieira EFS, Cestari AR, J. Colloid Interface Sci., 253(2), 243 (2002)
Cestari AR, Vieira EFS, dos Santos AGP, Mota JA, de Almeida VP, J. Colloid Interface Sci., 280(2), 380 (2004)
Ekici S, Isikver Y, Saraydin D, Polym. Bull., 57(2), 231 (2006)
Dadhaniya PV, Patel MP, Patel RG, Polym. Bull., 57(1), 21 (2006)
Adamson AW, Physical Chemistry of Surfaces, Wiley, New York, 1997, p. 584
Gregg SJ, Sink KSW, Adsorption, Surface Area and Porosity, Academic Press, London, 1982, pp. 248-257

[Referenced By]

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[1] Wang S, Boyjoo Y, Choueib A, Zhu ZH, Water Research, 39, 129 (2005)

[2] Saraydin D, Karadag E, Guven O, J. Appl. Polym. Sci., 79(10), 1809 (2001)

[3] Jeon CH, Makhaeva EE, Khokhlov AR, J. Polym. Sci. B: Polym. Phys., 37(12), 1209 (1999)

[4] Saha B, Streat M, Ind. Eng. Chem. Res., 44(23), 8671 (2005)

[5] Hashem A, Socker HH, Abdel Halim ES, Gamal A, Adsorpt. Sci. Technol., 23, 455 (2005)

[6] Delval F, Crini G, Bertini S, Filiatre C, Torri G, Carbohydr. Polym., 60, 67 (2005)

[7] Essawy HA, Ibrahim HS, React. Funct. Polym., 61, 421 (2004)

[8] Omidian H, Rocca JG, Park K, J. Control. Release, 102, 3 (2005)

[9] Griffith LG, Acta Mater., 48, 263 (2000)

[10] Shin J, Lim YM, Jeun JP, Nho YC, J. Ind. Eng. Chem., 13(6), 997 (2007)

[11] Kim KS, Vincent B, Cosgrove T, J. Ind. Eng. Chem., 12(1), 91 (2006)

[12] El-Hag Ali A, Shawky HA, Abd El Rehim HA, Hegazy EA, Eur. Polym. J., 39, 2337 (2003)

[13] Kang HW, Tabata Y, Ikada Y, Biomaterials, 20, 1339 (1999)

[14] You SJ, Ahn WS, Jang HS, Kang MI, Chun HJ, Lim YM, Nho YC, J. Ind. Eng. Chem., 13(1), 116 (2007)

[15] Sarmento B, Martins S, Ribeiro A, Veiga F, Neufeld R, Ferreira D, Int. J. Pept. Res. Ther., 12, 131 (2006)

[16] Wolk SK, Swift G, Paik YH, Yocom KM, Smith RL, Simon ES, Macromolecules, 27(26), 7613 (1994)

[17] Nakato T, Yoshitake M, Matsubara K, Tomida M, Kakuchi T, Macromolecules, 31(7), 2107 (1998)

[18] Neri P, Antoni G, Benvenuti F, Colola F, Gazzei G, J. Med. Chem., 16, 893 (1972)

[19] Kim JH, Lee JH, Yoon SW, J. Ind. Eng. Chem., 8(2), 138 (2002)

[20] Min SK, Kim SH, Kim JH, J. Ind. Eng. Chem., 6(4), 276 (2000)

[21] Yang J, Fang L, Tan TW, J. Appl. Polym. Sci., 102(1), 550 (2006)

[22] Sahiner N, Saraydin D, Karadag E, Guven O, Polym. Bull., 41(3), 371 (1998)

[23] dos Anjos FSC, Vieira EFS, Cestari AR, J. Colloid Interface Sci., 253(2), 243 (2002)

[24] Cestari AR, Vieira EFS, dos Santos AGP, Mota JA, de Almeida VP, J. Colloid Interface Sci., 280(2), 380 (2004)

[25] Ekici S, Isikver Y, Saraydin D, Polym. Bull., 57(2), 231 (2006)

[26] Dadhaniya PV, Patel MP, Patel RG, Polym. Bull., 57(1), 21 (2006)

[27] Adamson AW, Physical Chemistry of Surfaces, Wiley, New York, 1997, p. 584

[28] Gregg SJ, Sink KSW, Adsorption, Surface Area and Porosity, Academic Press, London, 1982, pp. 248-257