Correlation of measured excess enthalpies of binary systems composed of n-alkane+1-alkanol

Cheong Hoon Kwon; Jeong Won Kang

Korean Journal of Chemical Engineering, Vol.26, No.1, 240-245, January, 2009

DOI10.1007/s11814-009-0040-y Export Citation

Correlation of measured excess enthalpies of binary systems composed of n-alkane+1-alkanol

Cheong Hoon Kwon, and Jeong Won Kang^†

Department of Chemical and Biological Engineering, Korea University, 5 Ga, Anam-dong, Sungbuk-gu, Seoul 136-701, Korea

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The excess enthalpies of the binary mixture composed of n-alkane (n-octane, n-nonane, n-decane) and 1-alkanol (ethanol, 1-propanol, 1-butanol) have been measured by using a flow-type isothermal microcalorimeter (model CSC 4400, Calorimetry Science Corp., USA) at 313.15 K under atmospheric pressure. The measured excess enthalpy data were correlated by the Redlich-Kister equation and the nonrandom lattice fluid with hydrogen bonding (NLFHB) equation of state. Hydrogen bonding type specific parameters were introduced in the NLF-HB equation of state framework, and the effects of those parameters were investigated for excess enthalpy calculations. With two adjustable temperature-dependent interaction parameters, the NLF-HB equation represents the excess enthalpies for nine binary systems qualitatively.

Keywords:Excess Enthalpy;Isothermal Microcalorimeter;Equation of State;N-Alkane;1-Alkanol;Redlich-Kister Equation

[References]

Ochi K, Dai WB, Wada Y, Hayashi H, Kurihara K, Kojima K, Fluid Phase Equilib., 194, 919 (2002)
Kurihara K, Iguchi T, Ochi K, Kojima K, Fluid Phase Equilib., 144(1-2), 169 (1998)
Kang JW, Kim JY, Yoo KP, Lee CS, Fluid Phase Equilib., 151, 199 (1998)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)
Veytsman BA, J. Phys. Chem., 94, 8499 (1990)
Yeom MS, Park BH, Lee CS, Fluid Phase Equilib., 158-160, 143 (1999).
Lee CS, Yoo KP, Park BH, Kang JW, Fluid Phase Equilib., 187-188, 433 (2001)
Park BH, Kang JW, Yoo KP, Lee CS, Fluid Phase Equilib., 183-184, 111 (2001)
Pineiro A, Olvera A, Garcia-Miaja G, Costas M, J. Chem. Eng. Data, 46, 1274 (2001)
Ramalho RS, Rual M, Can. J. Chem. Eng., 46, 456 (1968)
Zhu SM, Shen SB, Benson GC, Lu BC, Fluid Phase Equilib., 94, 217 (1994)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 341 (1948)
Linde DR, Kehiaian HV, CRC handbook of thermophysical and thermochemical data, CRC Press, Boca Raton, Fl, USA (1994)

[Referenced By]

[Related Articles]

[1] Ochi K, Dai WB, Wada Y, Hayashi H, Kurihara K, Kojima K, Fluid Phase Equilib., 194, 919 (2002)

[2] Kurihara K, Iguchi T, Ochi K, Kojima K, Fluid Phase Equilib., 144(1-2), 169 (1998)

[3] Kang JW, Kim JY, Yoo KP, Lee CS, Fluid Phase Equilib., 151, 199 (1998)

[4] You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)

[5] You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)

[6] Veytsman BA, J. Phys. Chem., 94, 8499 (1990)

[7] Yeom MS, Park BH, Lee CS, Fluid Phase Equilib., 158-160, 143 (1999).

[8] Lee CS, Yoo KP, Park BH, Kang JW, Fluid Phase Equilib., 187-188, 433 (2001)

[9] Park BH, Kang JW, Yoo KP, Lee CS, Fluid Phase Equilib., 183-184, 111 (2001)

[10] Pineiro A, Olvera A, Garcia-Miaja G, Costas M, J. Chem. Eng. Data, 46, 1274 (2001)

[11] Ramalho RS, Rual M, Can. J. Chem. Eng., 46, 456 (1968)

[12] Zhu SM, Shen SB, Benson GC, Lu BC, Fluid Phase Equilib., 94, 217 (1994)

[13] Redlich O, Kister AT, Ind. Eng. Chem., 40, 341 (1948)

[14] Linde DR, Kehiaian HV, CRC handbook of thermophysical and thermochemical data, CRC Press, Boca Raton, Fl, USA (1994)