화학공학소재연구정보센터
Applied Chemistry, Vol.12, No.2, 365-368, November, 2008
화강암의 우라늄(VI)과 토륨(IV)의 수착에 대한 실험적 평가
An Experimental Study on U(VI) and Th(IV) Sorption by Granite
Batch type experiments of U(VI) and Th(IV) sorption on the crushed granite were carried out by measuring the distribution coefficient (Kd). Kd values for U(VI) sorption of granite were 3.38~11.02 mL/g and Kd,avg = 7.07 mg/L, when [U(VI)]tot = 1O^(-6)M. The Kd values for U(VI) were increased to the range of 17.10~234.24 mL/g (Kd,avg = 22.24 mL/g) as the dissolved U(VI) concentration was decreased to 10^(-7)M. On the other hand, Kd values for Th(IV) were measured to be in the range of 1,114.64~1,831.39 mL/g (Kd,avg = 1,586.63 mL/g) at [Th(IV)]tot = 1O^(-6), while Kd values for Th(IV) were 902.48~2,079.29 mL/g (Kd,avg = 1,353.80 mL/g) at [Th(IV)]tot = 10^(-7)M.