Korean Journal of Chemical Engineering, Vol.26, No.3, 783-790, May, 2009
Absorption of carbon dioxide into glycidyl methacrylate solution containing the triethylamine immobilized ionic liquid on MCM-41 catalyst
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An ionic liquid (TEA-MS41), triethylamine-immobilized on chloropropyl-functionalized MCM-41, was synthesized by a grafting technique through a co-condensation method and used as a catalyst in the reaction of carbon dioxide with glycidyl methacrylate (GMA). CO2 was absorbed into the heterogeneous system of the GMA solution and dispersed with solid particles of the catalyst in a batch stirred tank with a plane gas-liquid interface at 101.3 kPa. The absorption of CO2 was analyzed by using mass transfer accompanied by chemical reactions based on film theory. The proposed model fits the measured data of the enhancement factor to obtain the reaction rate constants. Solvents such as N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide influenced the reaction rate constants.
- Aresta M, Carbon dioxide recovery and utilization, Kluwer Academic Publishers, London (2003)
- Weissermel K, Arpe H, Industrial organic chemistry, Wiley-VCH, Weinheim, New York (1997)
- Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)
- Rokicki G, Makromol. Chem., 186, 331 (1985)
- Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
- Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406 (1990)
- Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
- Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Poly. Sci., Part A, Poly. Chem., 31, 939 (1993)
- Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)
- Starks CM, Liotta CL, Halpern M, Phase transfer catalysis, Chapman & Hall, New York (1994)
- Daraiswany LK, Sharma MM, Heterogeneous reaction: Analysis, example and reactor design, John Wiley & Sons, New York (1980)
- Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
- Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)
- Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
- Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)
- Burkett SL, Sim SD, Mann SJ, J. Chem. Soc., Chem. Commun., 1367 (1996)
- Lim MH, Blanford CF, Stein A, J. Am. Chem. Soc., 119(17), 4090 (1997)
- Fowler CE, Lebeau B, Mann S, J. Chem. Soc., Chem. Commun., 1825 (1998)
- Babonneau F, Leite L, Fontlupt S, J. Mater. Chem., 9, 175 (1999)
- Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2007)
- Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)
- Park SW, Choi BS, Park DW, Kim SS, J. Ind. Eng. Chem., 11(4), 527 (2005)
- Park SW, Lee JW, Stud. Surface Sci. Catal., 159, 345 (2006)
- Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
- Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)
- Park SW, Choi BS, Park DW, Kim SS, Lee JW, Korean J. Chem. Eng., 24(6), 953 (2007)
- Alper E, Al-Hamed A, Shaikh AA, Proc. Int. Chem. React. Eng. Conf., 2, 17 (1987)
- Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
- Reid RC, Prausnitz JM, Sherwood TK, The properties of gases and liquids, McGraw-Hill, New York (1977)
- Cussler EL, Diffusion, Cambridge University Press, New York (1984)
- Park SW, Kim KW, Sohn IJ, Kaseger CF, Sep. Purif. Technol., 19(1-2), 43 (2000)
- Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)
- Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)
- Brandrup J, Immergut EH, Polymer handbook, Second ed., John Wiley & Sons, New York (1975)
- Morrison RT, Boyd RN, Organic chemistry, Fourth ed, Allyn and Bacon, Inc, Toronto (1983)