The intramolecular charge transfer (ICT) reaction of 1-tert-butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6) in n-hexane and acetonitrile (MeCN) is investigated by picosecond fluorescence experiments as a function of temperature and by ferntosecond transient absorption measurements at room temperature. NTC6 in n-hexane is dual fluorescent from a locally excited (LE) and an ICT state, with a quantum yield ratio Phi'(lCT)/Phi(LE) of 0.35 at +25 degrees C and 0.67 at -95 degrees C, whereas in MeCN mainly an ICT emission is observed. From the temperature dependence of Phi(ICT)/Phi(LE) for NTC6 in n-hexane, an LEACT enthalpy difference AH of -2.4 kJ/mol is determined. For comparison, 1-isopropyl-6-cyaiio-1,2,3,4-tetrahydroquinoline (NIC6) is also investigated. This molecule does not undergo an ICT reaction, because of its larger energy gap Delta E(S-1,S-2). From the molar absorption coefficient epsilon(max) of NTC6 as compared with other aminobenzonitriles, a groundstate amino twist angle theta of similar to 22 degrees is deduced. The increase of epsilon(max) between n-hexane and MeCN indicates that theta decreases when the solvent polarity becomes larger. Whereas single-exponential LE fluorescence decays are obtained for NIC6 in n-hexane and MeCN, the LE and ICT decays of NTC6 in these solvents are double exponential. For NTC6 in n-hexane at -95 degrees C, with a shortest decay time of 20 ps, the forward (k(a) = 2.5 x 10(10) s(-1)) and backward (k(d) = 2.7 x 10(10) S-1) rate constants for the LE <-> ICT reaction are determined from the time-resolved LE and ICT fluorescence spectra. For NTC6 in n-hexane and MeCN, the excited-state absorption (ESA) spectrum at 200 fs after excitation is similar to the LE(ESA) spectra of NIC6 and 4-(dimethylamino)benzonitrile (DMABN), showing that LE is the initially excited state for NTC6. These results indicate that the LE states of NTC6, NIC6, and DMABN have a comparable molecular structure. The ICT(ESA) spectrum of NTC6 in n-hexane and MeCN resembles that of DMABN in MeCN, likewise indicating a similar ICT structure for NTC6 and DMABN. From the decay of the LE absorption and the corresponding growing-in for the ICT state of NTC6, it is concluded that the ICT state originates from the LE precursor and is not formed by direct excitation from So, nor via an SACT conical intersection. The same conclusion was made from the time-resolved (picosecond) fluorescence. spectra, where there is no ICT emission at time zero. The decay of the LE(ESA) band of NTC6 in n-hexane occurs with a shortest time tau(2) of 2.2 ps. The ICT reaction is much faster (tau(2) = 0.82 ps) in the strongly polar MeCN. The absence of excitation wavelength dependence (290 and 266 nm) for the ESA spectra in MeCN also shows that LE is the ICT precursor. With NIC6 in n-hexane and MeCN, a decay or growing-in of the femtosecond ESA spectra is not observed, in line with the absence of an ICT reaction involving an S-2/CT conical intersection.