In this work, we analyze the effect of intermolecular dipole-dipole interactions on Raman spectra of polyconjugated molecules. In particular, the behavior of push-pull polyenes has been studied. By means of density functional theory (DFT) calculations on isolated molecules and dimers, we have found that both the frequencies and intensities of the strongest Raman lines (R, mode) are strongly influenced by intermolecular interactions. The results have been rationalized within the effective conjugation coordinate (ECC) theory developed in the past. The calculations for different configurations have also shown that the Raman spectra are sensible to different intermolecular geometries, thus implying a possible application of vibrational spectroscopy to the study of supramolecular properties of polyconjugated systems. The comparison with the available experimental spectra confirms the results obtained with the DFT computations. Finally, a very simple mathematical model is proposed for the prediction of the Raman frequencies of interacting systems. From the knowledge of just a few quantities for the isolated molecule and of some geometrical parameters, an estimate of the frequency of the dimers can be obtained. Despite its simplicity, this model gives results in very good agreement with DFT calculations carried out explicitly on dimers in several different arrangements.