Journal of Power Sources, Vol.175, No.1, 630-634, 2008
High-temperature characteristics of advanced Ni-MH batteries using nickel electrodes containing CaF2
The high-temperature charge acceptance of Ni-MH batteries has been improved through the addition of calcium fluoride to the pasted nickel hydroxide electrode made using spherical Co(OH)(2)-coated nickel hydroxide powder. The charge acceptance of the Ni-MH battery at 60 degrees C is over 95% at 1 C charge/discharge rates. The charge acceptance at 60 degrees C remains at over 90% through 10 cycles. The use of Co(OH)2-coated Ni(OH)(2) plus a CaF2 addition to the positive electrode also significantly improved the high-temperature stability in terms of reduced gas evolution. (c) 2007 Elsevier B.V. All rights reserved.
Keywords:nickel-metal hydride battery;high-temperature charge acceptance;Co(OH)(2)-coated nickel hydroxide;cycle lifetime