화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.91, No.4, 1070-1076, 2008
Influence of precursor densification on strength retention of zirconia-coated Nextel (TM) 610 fibers
Strength degradation of Nextel (TM) 610 fibers by continuous liquid phase coating was investigated for four different zirconia precursors. The precursors differed regarding their chemical composition (with or without yttrium), phase composition (amorphous or crystalline), and decomposition behavior. Phase transformation and densification of the films were characterized and found to depend on the kind of precursor. Single fiber Weibull's strength was measured for calcination temperatures between 250 degrees and 1150 degrees C for all precursors. Each precursor had an individual degradation behavior. For an annealing temperature of 1150 degrees C highly damaged (similar to 1600 MPa) and undamaged (> 3300 MPa) fibers were obtained depending on the kind of precursor. Fiber degradation could be correlated to mechanical stresses. Stress concentration due to inhomogeneous film thickness distribution is proposed as the cause of fiber strength degradation. Full strength could be retained for porous coatings or coatings where stresses were reduced by phase transformation.