Journal of Colloid and Interface Science, Vol.323, No.2, 313-316, 2008
The Donnan potential-surface potential relationship for a cylindrical soft particle in an electrolyte solution
Transcendental equations, which avoid integration of the nonlinear Poisson-Boltzmann equations, are presented for obtaining the relationship between the Donnan potential and surface potential of a cylindrical soft particle (i.e., a polyelectrolyte-coated cylindrical particle) in a symmetrical electrolyte solution. Numerical results obtained by the present method are in excellent agreement with exact results obtained by solving the nonlinear cylindrical Poisson-Boltzmarm equations both inside and outside the polyelectrolyte layer. (c) 2008 Elsevier Inc. All rights reserved.