Significant progress has been made in the past decade in plasma nitriding with a majority of the research work focusing on improving hardness and wear resistance of the nitrided surface through the reduction of nitriding temperature, pressure or time. Hard-solid lubricating coatings have also been extensively studied for lowering the wear rate and coefficient of friction of traditional hard coatings such as TiN by the combined effect of hardness and solid lubrication. In this study, the wear characteristics of low-temperature plasma-nitrided steel substrate performed using a Saddle-field fast atom beam source and TiN + MoSx hard-solid lubricant coating deposited by a closed-field magnetron-sputtering technique have been investigated. The thin hard layer in plasma-nitrided substrates exhibited much higher hardness and lower wear compared to the untreated substrate in pin-on-disc wear testing. In addition, the study of the wear track morphology of the nitrided samples evidenced significant reduction of deeper ploughing and plastic deformation due to higher hardness and load supporting of the nitrided layer. On the other hand, due to the incorporation of MoS2 in TiN coating, the wear resistance and coefficient of friction were greatly improved in TiN + MoSx coating compared to pure TiN coating. In contrast to TiN coating, a relatively smoother wear track with less abrasive wear also supported the beneficial effects of adding MoS2 in TiN coating.